Freeze cast porous membrane catalyst for hydrogen production via oxy-reforming

In this work, porous catalytic membrane with tailored microstructure has been developed for the production of hydrogen from oxy-reforming process. Porous membranes have produced by freeze-casting ceria-based powders using camphene as solvent. The process parameters optimized in terms type and amount dispersant to obtain homogeneous stable ceramic suspension suitable process, while freezing temperature was chosen on basis porosity final samples. obtained freeze cast sample showed very high levels (≈ 80%) good gas permeability (1.0 × 10−11 m2). structure finally evaluated catalyst reaction methane showing conversions (up 90%) production. use a unique other than pelleted catalysts allowed obtaining smooth thermal profiles without evidence endothermic or exothermic peaks.